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The…Highly efficient and stable blue phosphorescent iridium complex with a bridging pyrazine derivative via triplet energy transfer.
New iridium(III) complex Ir-H0MP is synthesized by adding H2O2 to an iridium complex Ir-OtBuMP with a bridging pyrazine derivative 2-(4′-tert-butylphenyl)-2-methyl-4-(4′-tert-butylphenyl)pyrazine. The Ir-H0MP complex shows efficient and stable blue phosphorescence with the emission at 471 nm, which is attributed to T1-T3 triplet excitations. The quantum efficiency reaches 86%. DFT calculations show that the calculated triplet energy of Ir-H0MP is about 1.26 eV, which is larger than that of Ir-OtBuMP itself (0.92 eV) and Ir-OtBuMP complex with 2-(4′-tert-butylphenyl)-2-methyl-4-(2′-methyl-3′-naphthyl)pyrazine, a more rigid acceptor (0.74 eV).Share 0 SHARES
SINGLES over 40s are now requiring marriage in order to have children, according to the organisation responsible for the publication of marriage ads in the UK.
The National Marriage Editor’s Council for People Over 40, an organisation dedicated to rethinking and improving upon the system, said it was not sure when it became so much easier to find a partner, but said the decision was as a result of a lot of change in the way people in their mid-40s spend their time.
“There’s a gradual shift where you’ll see the level of activity start to decline as you get older, and around 40 is when most people tend to sort of end their active careers and start to plan for things,” one man over 40, who wishes to remain anonymous, told WWN.
“So, for some people they might spend more time in their leisure time, and when you don’t have children it’s a bit easier to be single and just have that time,” he added.
The current spike in marriages being formed by the over 40s comes as a result of couples not having children.
“It’s a little bit of a new trend. People aren’t really too
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